The star is the first to wear a frock from Valentino’s fall 2011 collection, and she looks stunning in the embellished halter dress — is this premiere perfect or what?

Jennifer Aniston may have stepped out of her comfort zone in an edgy leather frock earlier in the day, but for the UK premiere of Horrible Bosses the star dazzled in Valentino couture from the fall 2011 collection. Jen is the first star to show off a look from the collection, and considering she’s a huge fan of the brand the look is such a signature Jen move.

I like how she ditched her slew of black dresses for a light frock more suited for summer, and I liked the way the embellished halter dress highlighted her toned arms. Jen completed the get-up with a pair of white open-toe booties — while I think white shoes can be tricky to pull off, I also appreciate the way Jen switched up her style and left her strappy sandals at home.

What did you think of Jen’s premiere get-up?

Katrina Mitzeliotis